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RICOH D110A MSDS(Material Safety Data Sheet)

RICOH D110A MSDS(Material Safety Data Sheet)
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Safety Data Sheet (ISO form)

1. Product and Company Identification
Product Name : RICOH THERMAL TRANSFER RIBBON TYPE D110A
General Use : For Printer
MSDS Number :
Company Name : Ricoh Company,Ltd.
Department : Environment Safety Center, Corporate Environment Division
Address : 146-1 Nishisawada, Numazu-shi, Shizuoka-ken, 410-0007 Japan
Telephone Number : 055-920-1470, Japan
Telefax Number : 055-920-1479, Japan
E-mail : msdsinfo@nts.ricoh.co.jp

2. Composition/Information on Ingredients
Substance or Preparation : Preparation
Chemical Nature : Ingredients / Chemical Formula / CAS.No. / Contents(%)
- Polyester Film / (C10H8O4)n / 25038-59-9 / 76
- Cellulose Resin / Confidential / Confidential / 5
- Wax / Confidential / Confidential / 16
- Carbon Black / C / 1333-86-4 / 3
This product does not contain any of the following substances as ingredients.
Cadmium, Hexavalent Chromium, Mercury, Lead, Polybrominated biphenyls (PBB), Polybrominated diphenyleters (PBDE).
Hazardous Ingredients Information ;
Chemical Name : Carbon Black
CAS Number : 1333-86-4
EEC Number : 215-609-9
OSHA Z-Tables (USA) : 3.5mg/m3
ACGIH-TLV : 3.5mg/m3
NTP (USA) : Not listed
IARC Monographs : Group 2B
Symbol (EU) : Not listed
R-Phrase (EU) : Not listed
DFG-MAK : III 3B
OELs-TWA (Australia) : 3.0mg/m3
California Proposition 65 (USA) : Listed

3. Hazards Identification
The Most Important Hazards ;
Adverse Human Health Effects : There are no significant hazards expected with intended use.
Environmental Effects : There are no significant hazards expected with intended use.
Physical and Chemical Hazards : There are no significant hazards expected with intended use.
Specific Hazards ;
There are no significant hazards expected with intended use.
Main Symptoms ;
Acute Inhalation Toxicity : Under normal use conditions, there is no possibility to inhale the particle of ink.
Acute Oral Toxicity : Low acute toxicity in animal experiment.
Acute Eye Irritation : Under normal use conditions, there is no possibility to enter into the eye.
Acute Skin Irritation : May be non-irritant.
Sensitization : From test no apparent significant hazards are expected.
Chronic Effect : Under normal use conditions, there is no possibility to inhale the particle of ink.
Carcinogenicity :
Carbon black contained in this product is classified to Group 2B of IARC as the result of inhalation test in use of rat.
This is due to the fact that rat alone showed lung tumor in the animal experiment under very high concentration.
During a normal use of this product, design of the cartridge proves it impossible to have powder carbon black released to the air.
Intake from the mouth and skin does not show carcinogenicity.
The Classification of The Chemical Product :
This preparation is not classified as dangerous according to Directive 1999/45/EC.

4. First-Aid Measures
Inhalation : Not applicable
Skin Contact : There is no problem if it touches skin under normal use conditions.
Eye Contact : Flush with a large amount of water until particles are removed. Seek medical advice.
Ingestion : Induce vomiting. Seek medical attention.
Notes to a physician : Not applicable

5. Fire-Fighting Measures
Extinguishing Media : CO2,dry chemicals,foam or water.
Extinguishing Media to Avoid : Not applicable.
Specific Hazards : Not applicable
Specific Method : No special fire protecting method is required. Sprinkling or fire extinguishers can be used.
Protection of Fire-fighters : Wear gloves, glasses, a mask if necessary.

6. Accidental Release Measures
Personal Precautions : Not applicable
Environment Precautions : Not applicable
Methods for Cleaning Up : Not applicable

7. Handling and Storage
Handling ;
Technical Measures/Precautions : Not applicable
Safe Handling Advice : In order to protect quality, do not wet with water, oil or medicine.
Storage ;
Technical Measures : Not applicable
Storage Conditions :
Keep out of reach of children.
In order to protect quality, avoid direct sunlight and humidity and store it indoor.
Packaging Material : Not applicable
Specific Use(s) ;
Image formation in printing machines.

8. Exposure Controls/Personal Protection
Technical Measures : Use adequate ventilation. None required with intended use.
Control Parameters
- USA OSHA PEL (TWA) : Not applicable
- ACGIH TLV (TWA) : Not applicable
- DFG MAK : Not applicable
Personal Protection ;
Respiratory Protections : None required in normal use.
Hand Protection : None required in normal use..
Eye Protection : None required in normal use.
Skin and Body Protection : None required in normal use.
Hygiene Measures : Wash hands after handling.

9. Physical and Chemical Properties
Appearance
- Physical State : Solid
- Form : Ribbon
- Colour : Black
- Odour : No odour
Information
- pH : Not applicable
Specific Temperatures/Temperature Ranges at Which Changes in Physical State Occur
- Boiling Point (degrees centigrade) : Not applicable
- Melting Point (degrees centigrade) : (Softening point) Approx.70
Decomposition Temperature (degrees centigrade) : Not available
Flash Point (degrees centigrade) : Not applicable
Explosion Properties (degrees centigrade) : This product is considered a nonexplosive material under normal use.
Vapor Pressure (Pa) : Not applicable
Vapor Density(AIR=1) : Not applicable
Density (g/cm3) : Not available
Measuring Temp (degrees centigrade) : -
Solubility ;
Water Solubility (g/L) : Insoluble
Other solvent Solubility (g/L) : Not available
Measuring Temp (degrees centigrade) : -
Octanol/Water Partition Coefficient : Not available
Other Information ;
Flammability : Not flammable
Viscosity (Pa?s) : Not applicable
Volatile (%) : Below 0.1

10. Stability and Reactivity
Stability : Stable
Hazardous Reaction : There is no significant hazardous reaction expected with intended use.
Conditions to Avoid : Not applicable in normal use.
Materials to Avoid : Not applicable in normal use.
Hazardous Decomposition Products : Decomposition products will not occur.

11. Toxicological Information
Acute Toxicity ;
Acute Oral Toxicity (LD50) : 2000 or over (Rat)
Acute Dermal Toxicity : Not available
Acute Inhalation Toxicity : Not available
Local effects ;
Acute Skin Irritation(PII) : Non-irritant
Acute Eye Irritation : Not available (Ingredients are not classified as dangerous according to Directive 67/548/EEC.)
Sensitization ;
Acute Allergenic Effects : 0 %
Specific Effects ;
Carcinogenicity :
Carbon black contained in this product is classified to Group 2B of IARC as the result of inhalation test in use of rat.
This is due to the fact that rat alone showed lung tumor in the animal experiment under very high concentration.
During a normal use of this product, design of the cartridge proves it impossible to have powder carbon black released to the air.
Intake from the mouth and skin does not show carcinogenicity.
Mutagenicity : Negative
Reproduction Toxicity : Does not contain substances listed as hazardous to reproductive health.

12. Ecological Information
Mobility : No data are available on the adverse effect one environment.
Persistence/Degradability : Not available
Bioaccumulation : Not available
Ecotoxicity ;
Acute Toxicity for Fish(LC50) : Not available
Acute Toxicity for Daphnia(EC50) : Not available
Algae Inhibition Test(IC50) : Not available

13. Disposal Consideration
General information : Used ribbon should be disposed in an environmentally appropriate manner and accordance with governmental regulations.
Disposal methods :
Disposal recommendations are based on material as supplied.
Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal.
Confirm disposal procedures with local regulations.
Precautions : Not applicable

14. Transport Information
International Regulations ;
Land Transport
- RID/ADR : Not applicable
- DOT 49 CFR : Not applicable
- ADNR : Not applicable
Sea Transport
- IMDG Code : Not applicable
Air Transport
- ICAO-TI/IATA-DGR : Not applicable
- The UN Classification Number : Not applicable
Specific Precautionary Transport Measures and conditions ;
None in normal use.

15. Regulatory Information
Regulations
EU Information ;
Information on the label (1999/45/EC and 67/548/EEC)
- Symbols & Indications : Not required
- R-Phrase : Not required
- S-Phrase : Not required
- Special Precautions under 1999/45/EC Annex V : Not required
76/769/EEC : This product complies with applicable rules and regulations under 76/769/EEC
304/2003/EC : Not regulated
US Information ;
Information on the label : Not required
TSCA (Toxic Substances Control Act) : This product complies with all applicable rules and regulations under TSCA.
SARA Title III
- 313 Reportable Ingredients : Not regulated
- California Proposition 65 : Not regulated
Canada Information ;
WHMIS Controlled product : Not a controlled product

16. Other Information
NFPA Hazard Rating : National Fire Protection Agency (USA)
- Health ; 1, Flammability ; 1, Reactivity ; 0
HMIS Rating : The National Paint and Coating Association (USA)
- Health ; 1, Flammability ; 1, Reactivity ; 0
Literature References :
- ANSI Z400.1-1993
- ISO 11014-1
IARC (1996) "IARC Monograph on the Evaluation of the Carcinogenic Risk of Chemicals to Humans, Vol.65,
Printing Process and Printing Inks, Carbon Black and Some Nitro Compounds", Lyon, pp149-261
H. Muhle, B. Bellman, O. Creutzenberg, C. Dasenbrock, H. Emst, R. Kilpper, J.C. MacKenzie, P. Morrow,
U. Mohr, S. Takenaka and R. Mermelstein(1991) "Pulmonary Response to Toner upon Chronic Inhalation
Exposure in Rats" Fundamental and Applied Toxicology 17, pp 280-299
IARC (2008) "IARC Monograph on the Evaluation of the Carcinogenic Risk of Chemicals to
Humans, Vol.93"
NIOSH CURRENT INTELLIGENCE BULLETIN "Evaluation of Health Hazard and Recommendation for Occupational Exposure to Titanium Dioxide DRAFT"
ACGIH-TLV : Threshold Limit Values for Chemical Substances and Physical Agents and Biological Exposure Indices
OSHA Z-Tables : US Department of Labor, 29CFR Part 1910 , Tables Z-1, Z-2, and Z-3
NTP (USA) : US Department of Health and Human Services National Toxicology Program Annual Report on Carcinogens
DFG-MAK : DFG List of MAK and BAT Value
Symbol (EC) : EU Directive 67/548/EEC
91/155/ EEC : EU Directive 91/155/ EEC
1999/45/EC Annex V : EU Directive 1999/45/EC
76/769/ EEC : EU Directive 76/769/ EEC
EC 304/2003 :
Regulation (EC) No 304/2003 of the European Parliament and of the Council of 28 January 2003 concerning the export and import of dangerous chemicals
WHMIS Controlled product : Canada Workplace Hazardous Information System
OELs-TWA (Australia) : Guidance Note on the Interpretation of Exposure Standards for Atmospheric Contaminants in the Occupational Environment [NOHSC: 3008 (1995)]
Abbreviations ;
OSHA PEL : PEL (Permissible Exposure Limit) under Occupational Safety and Health Act
ACGIH-TLV : TLV (Threshold Limit Values) under American Conference of Governmental Industrial Hygienists
DFG-MAK : MAK (Maximale Arbeitsplatz Konzentrationen) by Deutsche Forschungs Gemeinschaft
RoHS : Restriction of the use of certain Hazardous Substances in Electrical and Electronic Equipment
TWA : Time Weighted Average
IARC : International Agency for Research on Cancer
NTP : National Toxicology Program
WHMIS : Workplace Hazardous Information System
NOHSC : National Occupational Health and Safety Commission Act 1985
Disclaimer :
This information is furnished without warranty, express or implied, except that it is accurate to the best knowledge of RICOH COMPANY, LTD.
It relates only to the specific material designated herein, and does not relate to use in combination with any other material or process.
RICOH COMPANY, LTD assumes no legal responsibility for use or reliance upon this information.
hion hion · 2019-05-27 14:32 · 조회 3670
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