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GENERAL SD-100(M) MSDS(Material Safety Data Sheet)

GENERAL SD-100(M) MSDS(Material Safety Data Sheet)
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SAFETY DATA SHEET

Product name : THERMAL TRANSFER RIBBON SD-100(M)
Date Prepared : Dec.28.2017
SDS Number : 17C022
Revision Date : -

1. PRODUCT AND COMPANY IDENTIFICATION
Product Name : THERMAL TRANSFER RIBBON SD-100(M)
Recommended use : Thermal transfer ribbon
Company : GENERAL CO., LTD.
Address : 18, Satsukigaoka, Minakuchi-cho, Koka-shi, Siga 528-0062, Japan
Telephone number : +81-748-65-2260
Fax number : +81-748-63-1922
E-mail : qa_1@general.co.jp
Emergency telephone number : +81-748-65-2260

2. HAZARDS IDENTIFICATION
GHS Classification of the substance or mixture : This product is not classified.
GHS Label Elements ;
- Hazard pictogram : Not applicable
- Signal word : Not applicable
- Hazard statements : Not applicable
- Precautionary statements : Not applicable
Other hazards : None known

3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance or Mixture : Mixture
Ingredients :
Components / CAS No. / Concentration (wt%)
[Ink] Resin / Confidential / 10 - 14
Carbon Black / 1333-86-4 / 4 - 7
Carnauba Wax / 8015-86-9 / 4 - 8
Paraffin Wax / 8002-74-2 / 4 - 7
Extender Pigment / Confidential / 2 - 5
[Base Film] Polyethylene Terephthalate / 25038-59-9 / 65 - 70

4. FIRST-AID MEASURES
Description of first aid measures
Inhalation : Get medical advice/attention if you feel unwell.
Skin contact : Wash thoroughly with soap and water. If skin irritation occurs : Get medicaladvice/attention.
Eye contact : Rinse with plenty of water and seek medical advice if any irritation remains.
Ingestion : Wash mouth with water and get medical advice.
Most important symptoms and effects, both acute and delayed : No further relevant information available.
Recommendations for immediate medical care and special treatment needed
Notes to physician : No further relevant information available.

5. FIRE-FIGHTING MEASURES
Extinguishing media
- Suitable extinguishing media : Water, Foam, CO2, Dry Chemical and others.
- Unsuitable extinguishing media : No information available.
Specific hazards arising from the substance or mixture : Carbon monoxide, carbon dioxide (CO2) will form in fire.
Special protective equipment for firefighters :
Fight fire from the windward side if possible.
Fire fighters should wear suitable protective clothing and self-contained breathing apparatus.

6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures : Wear appropriate personal protective equipment as specified in section 8.
Environmental precautions : Do not release into soil, sewers, river, or the public water courses.
Methods and materials for containment and cleaning up : Sweep up and collect spilled product.

7. HANDLING AND STORAGE
Handling ;
- Handling :
Handle in well ventilated area. Prohibition of dropping and throwing.
Because the film roll products are heavy, be careful about downfall.
Static electricity may take place during processing.
So, use of static eliminators is recommended.
- Hygiene measures : Wash hands thoroughly after handling.
Storage ;
Keep away from heat and direct sunlight.
Store in cool, dry, well-ventilated area.
Safe Packaging Material ; No information available.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure Guidelines ;
Components / CAS No. / OSHA PEL / ACGIH TLV
- Paraffin Wax / 8002-74-2 / - / (fume) 2 mg/m3
- Carbon Black / 1333-86-4 / 3.5 mg/m3 / 3 mg/m3
Engineering controls ;
Engineering measures : None required under normal conditions of use.
Personal protective equipment ;
Respiratory protection : None required under normal conditions of use.
Hand protection : It is not required in particular, but wearing of protection gloves is preferable to prevent soiling of hands.
Eye protection : None required under normal conditions of use.
Skin and body protection : None required under normal conditions of use.

9. PHYSICAL AND CHEMICAL PROPERTIES
Physical state : Ribbon
Color : Black
Odor : None
pH : No data available
Melting point : Above 250 degrees C (Film)
Boiling point : No data available
Flash point : No data available
Evaporation rate : No data available
Flammability (solid, gas) : Combustibles
Upper explosion limit : No data available
Lower explosion limit : No data available
Vapor pressure : No data available
Vapor density : No data available
Relative density : Approx. 1.4 (Film)
Water solubility : Insolubility
Partition coefficient : n-octanol/water : No data available
Auto-ignition temperature : Above 480 degrees C (Film)
Decomposition temperature : No data available
Viscosity : No data available

10. STABILITY AND REACTIVITY
Reactivity : No hazardous reactions with proper storage and handling.
Chemical stability : The product is stable under normal conditions.
Possibility of hazardous reactions : No information available.
Conditions to avoid : No information available.
Incompatible materials : No information available.
Hazardous decomposition products : No dangerous decomposition products known.

11. TOXICOLOGICAL INFORMATION
Acute toxicity ;
- Acute toxicity (oral) :
LD50 (rat) 15400 mg/kg, >8000 mg/kg [Carbon black]
LD50 (rat) >5000 mg/kg [Paraffin wax]
- Acute toxicity (dermal) :
LD50 (rabbit) >3000 mg/kg [Carbon black]
LD50 (rabbit) >3600 mg/kg [Paraffin wax]
Skin corrosion/irritation : No data available
Serious eye damage/eye irritation : (rabbit) slightly irritant, mild irritant [Paraffin Wax]
Respiratory or skin sensitization : (Guinea pig) Not sensitizer (OECD 406 Buehler test) [Similar product data]
Germ cell mutagenicity : No data available
Carcinogenicity ;
- NTP : Not listed.
- IARC : Carbon black: 2B
- EPA : Not listed.
- ACGIH : Carbon black: A3
This classification is given to chemicals for which there is inadequate human evidence, but sufficient animal evidence on which to base an opinion of carcinogenicity.
The classification is based upon the development of lung tumors in rats receiving chronic inhalation exposures to free carbon black at levels that induce particle overload of the lung.
Studies performed in animal models other than rats did not show any association between carbon black and lung tumors.
Reproductive toxicity : No data available
Specific target organ systemic toxicity - Single exposure : Fumes may cause mild irritation. [Paraffin Wax]
Specific target organ systemic toxicity - Repeated exposure :
Epidemiologic studies of workers in the carbon black producing industry in the U.S. and in Western Europe show no significant adverse health effect due to occupational exposure to carbon black. [Carbon black]
Aspiration hazard : No data available

12. ECOLOGICAL INFORMATION
Ecotoxicity
- Toxicity to fish : No data available
- Toxicity to crustacea : No data available
- Toxicity to algae/aquatic plants : No data available
Persistence and degradability : No data available
Bioaccumulation : No data available
Mobility in soil : No data available

13. DISPOSAL CONSIDERATIONS
Appropriate disposal methods :
Dispose of waste material in accordance with local, state and federal pollution regulations.
Contaminated packaging :
When disposing of an empty container, dispose after removing contents materials completely.
Dispose of this material and its container according to your country law.

14. TRANSPORT INFORMATION
International Regulations ;
- UN number : Not regulated
- UN proper shipping name : Not regulated
- Class : Not regulated
- Packing group : Not regulated
Sea transport ;
IMDG-Code : Not dangerous goods.
Air transport ;
ICAO-TI/IATA-DGR : Not dangerous goods.
Land transport ;
DOT : Not dangerous goods.
ADR/RID : Not dangerous goods.

15. REGULATORY INFORMATION
Follow all regulations in your country.

16. OTHER INFORMATION
Literature Reference ;
- SDS of raw material manufacturer
- NITE : Chemical Risk Information Platform
- 3E : Ariel Research Tool
- ECHA : Information on Chemicals
Revision date : -
Further information :
The information contained herein is based on the current knowledge.
This Safety Data Sheet is intended to describe our products in correctness of safety requirements.
It should not therefore be construed as guaranteeing specific properties.
The data applies to only usual handing.
hion hion · 2019-06-03 15:32 · 조회 3948
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